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DAT - Dental Admission General Chemistry: Acid-Base Chemistry Flashcards

6 cards from real DAT practice questions. Tap to flip, then mark Knew It or Still Learning — missed cards come back until you master them.

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  1. A buffer solution resists pH changes upon addition of small amounts of:

    Answer: Strong acid or strong base

    A buffer resists pH changes when small amounts of strong acid or strong base are added by neutralizing them through its weak acid/conjugate base equilibrium.

  2. The Henderson-Hasselbalch equation for a buffer is: pH =

    Answer: pKa + log([A⁻]/[HA])

    The Henderson-Hasselbalch equation pH = pKa + log([A⁻]/[HA]) relates buffer pH to the pKa and ratio of conjugate base to weak acid.

  3. Which combination forms an effective buffer?

    Answer: CH₃COOH and CH₃COONa

    An effective buffer requires a weak acid and its conjugate base, such as acetic acid (CH₃COOH) and sodium acetate (CH₃COONa).

  4. The bicarbonate buffer system in blood maintains physiological pH at approximately:

    Answer: 7.4

    The H₂CO₃/HCO₃⁻ buffer system is the primary blood buffer, maintaining pH at approximately 7.4 (normal range 7.35–7.45).

  5. A buffer is most effective when the solution pH is close to:

    Answer: The pKa of the weak acid component

    A buffer provides maximum buffering capacity when pH is within ±1 unit of the weak acid's pKa.

  6. What happens to pH when the buffer capacity is exceeded by addition of a large amount of strong base?

    Answer: pH increases dramatically once the buffer capacity is exhausted

    Once all the weak acid component is consumed, additional strong base causes a sharp, dramatic increase in pH.